Transient anions of cis- and trans-cyclooctene studied by electron-impact spectroscopy
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چکیده
منابع مشابه
Transient anions of cis- and trans-cyclooctene studied by electron-impact spectroscopy.
The effect which deformation of the double bond in trans-cyclooctene (TCO), compared to cis-cyclooctene (CCO), has on its negative ion - and indirectly on the π* virtual orbital - was studied by electron-impact spectroscopy. Differential elastic and vibrational excitation cross sections were measured at a scattering angle of θ = 135°. The vertical attachment energy (VAE) derived from the vibrat...
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The synthesis of trans-[{Rh(μ-Cl)(CO)(coe)}2] (1) was described by Varshavsky et al. some years ago [1, 2], but no crystal structure of this compound was reported. In an attempt to probe a possible convenient synthesis of [{Rh(μ-Cl)(CO)2}2] from the precursor [{Rh(μ-Cl)(coe)2}2] and carbon monoxide in diethyl ether, we found that the target complex was not available by this method. Instead, the...
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ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2015
ISSN: 1463-9076,1463-9084
DOI: 10.1039/c4cp04083j